一次相転移のカイネティクス

防衛大学校材料物性工学教室　阿部　洋
筑波大学物理工学系　大嶋建一

Kinetics of the First-Order Phase Transition.

H.Abe and K.Ohshima¹
Department of Materials Science and Engineering, National Defense Academy, Yokosuka 239, Japan
¹Institute of Applied Physics, University of Tsukuba, Tsukuba 305, Japan

J.Cryst.Soc.Jpn, Vol.38, pp151-159(1995).

　A characteristic waiting time appears at fixed temperature above T_c or M_s for elements, alloys and polymers, where T_c is the usual first-order phase transition temperature and M_s is the normal martenstic phase transition temperature. This waiting time is called incubation time and related with the nucleation probability derived from a nucleation barrier. That is why nucleation process is regarded as thermal activated process at the non-equilibrium state. In particular, such a long incubation time of In-Tl alloys has a good agreement with experimental results by using Roitburd method. Furthermore, detail and acurate experiments enable us to be aware that two dimensional growth occurs above T_p, where peculiar temperature, T_p, control the time development of diffraction patterns and appears above M_s in this system. 　In contras to phonon soft model, incubation time is essential property of the first-order phase transition and the key to resolve nucleation and growth process.

図.11 Roitburd による二次元の多層ドメイン・マルテンサイト.47) それぞれ、バリアント1からなるドメイン1とバリアント2からなるドメイン2が周期的に並んでいる。

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